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March 6, 2024

Bottom-Illuminated Photothermal Nanoscale Chemical Imaging with a Flat Silicon ATR in Air and Liquid

We demonstrate a novel approach for bottom-illuminated atomic force microscopy and infrared spectroscopy (AFM-IR). Bottom-illuminated AFM-IR for measurements in liquids makes use of an attenuated total […]
February 13, 2024

Tuning the Microenvironment of Water Confined in Ti3C2Tx MXene by Cation Intercalation

The local microenvironment has recently been found to play a major role in the electrocatalytic activity of nanomaterials. Modulating the microenvironment by adding alkali metal cations […]
January 24, 2024

Nanostructured Black Silicon as a Stable and Surface-Sensitive Platform for Time-Resolved In Situ Electrochemical Infrared Absorption Spectroscopy

Attenuated total reflection surface-enhanced infrared absorption spectroscopy (ATR-SEIRAS) is a powerful method for probing interfacial chemical processes. However, SEIRAS-active nanostructured metallic thin films for the in […]
January 17, 2024

Pairing Synchrotron Radiation with an ATR-Integrated Microreactor for In-Situ Spatiotemporal Characterization of Chemical Reactions

Microfluidic devices consist of microfabricated structures designed to control minuscule volumes of fluid with exceptional precision. The growth of this field has allowed researchers to miniaturize […]
November 27, 2023

Development and Characterization of Electrodes for Surface-Specific Attenuated Total Reflection Two-Dimensional Infrared Spectroelectrochemistry

Electrochemical interfaces still have remaining mysteries surrounding the interfacial region of the electrical double layer, despite being prevalent throughout the energy and water remediation industries. The […]
October 30, 2023

Unexpected Reduction of a Coordinated Diazapyridinophane Ligand Bound to Chromium(III) Ion Leading to Delocalization of the Unpaired Electron across Two Isolated Pyridine Units

In the tetraazamacrocyclic ligand N,N’-dimethyl-2,11-diaza-[3.3](2,6)pyridinophane (L-N4Me2), the two pyridine units are separated from each other by sp3-hybridized triatomic bridges. Such electronically isolated pyridine moieties are considerably less […]
October 9, 2023

Probing Complex Chemical Processes at the Molecular Level with Vibrational Spectroscopy and X-ray Tools

Understanding the origins of structure and bonding at the molecular level in complex chemical systems spanning magnitudes in length and time is of paramount interest in […]
September 22, 2023

Impact of Electrolyte Composition on Bulk Electrolysis of Furfural over Platinum Electrodes

Partial oxidation of furanic biomass derivatives such as furfural is of interest for the sustainable production of chemicals including furoic acid, maleic acid, and 2,5-furandicarboxylic acid […]
July 8, 2023

Microfabrication Process Development for a Polymer-Based Lab-on-Chip Concept Applied in Attenuated Total Reflection Fourier Transform Infrared Spectroelectrochemistry

Micro electro-mechanical systems (MEMS) combining sensing and microfluidics functionalities, as are common in Lab-on-Chip (LoC) devices, are increasingly based on polymers. Benefits of polymers include tunable […]
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