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January 24, 2024

Nanostructured Black Silicon as a Stable and Surface-Sensitive Platform for Time-Resolved In Situ Electrochemical Infrared Absorption Spectroscopy

Attenuated total reflection surface-enhanced infrared absorption spectroscopy (ATR-SEIRAS) is a powerful method for probing interfacial chemical processes. However, SEIRAS-active nanostructured metallic thin films for the in […]
January 17, 2024

Pairing Synchrotron Radiation with an ATR-Integrated Microreactor for In-Situ Spatiotemporal Characterization of Chemical Reactions

Microfluidic devices consist of microfabricated structures designed to control minuscule volumes of fluid with exceptional precision. The growth of this field has allowed researchers to miniaturize […]
November 27, 2023

Development and Characterization of Electrodes for Surface-Specific Attenuated Total Reflection Two-Dimensional Infrared Spectroelectrochemistry

Electrochemical interfaces still have remaining mysteries surrounding the interfacial region of the electrical double layer, despite being prevalent throughout the energy and water remediation industries. The […]
October 30, 2023

Unexpected Reduction of a Coordinated Diazapyridinophane Ligand Bound to Chromium(III) Ion Leading to Delocalization of the Unpaired Electron across Two Isolated Pyridine Units

In the tetraazamacrocyclic ligand N,N’-dimethyl-2,11-diaza-[3.3](2,6)pyridinophane (L-N4Me2), the two pyridine units are separated from each other by sp3-hybridized triatomic bridges. Such electronically isolated pyridine moieties are considerably less […]
October 9, 2023

Probing Complex Chemical Processes at the Molecular Level with Vibrational Spectroscopy and X-ray Tools

Understanding the origins of structure and bonding at the molecular level in complex chemical systems spanning magnitudes in length and time is of paramount interest in […]
September 22, 2023

Impact of Electrolyte Composition on Bulk Electrolysis of Furfural over Platinum Electrodes

Partial oxidation of furanic biomass derivatives such as furfural is of interest for the sustainable production of chemicals including furoic acid, maleic acid, and 2,5-furandicarboxylic acid […]
July 8, 2023

Microfabrication Process Development for a Polymer-Based Lab-on-Chip Concept Applied in Attenuated Total Reflection Fourier Transform Infrared Spectroelectrochemistry

Micro electro-mechanical systems (MEMS) combining sensing and microfluidics functionalities, as are common in Lab-on-Chip (LoC) devices, are increasingly based on polymers. Benefits of polymers include tunable […]
July 2, 2023

Methods for Infrared Spectral Sensing of Chemical and Biological Matter at the Microscale : Theory and Experiments

The use of infrared spectroscopy for biological and clinical applications has been demonstrated by a large number of proof-of-principle studies showing a high sensitivity and specificity […]
April 1, 2023

Rapid detection of phosphorus in water using silicon attenuated total reflectance infrared spectroscopy coupled with the algorithms of deconvolution and partial least squares regression

Conventional methods for phosphorus (P) analysis are time-consuming and laborious, which limited the application of rapid P monitoring in water. In this study, silicon (Si) was applied to […]
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