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July 2, 2023

Methods for Infrared Spectral Sensing of Chemical and Biological Matter at the Microscale : Theory and Experiments

The use of infrared spectroscopy for biological and clinical applications has been demonstrated by a large number of proof-of-principle studies showing a high sensitivity and specificity […]
April 1, 2023

Rapid detection of phosphorus in water using silicon attenuated total reflectance infrared spectroscopy coupled with the algorithms of deconvolution and partial least squares regression

Conventional methods for phosphorus (P) analysis are time-consuming and laborious, which limited the application of rapid P monitoring in water. In this study, silicon (Si) was applied to […]
October 19, 2022

Probing growth of metal–organic frameworks with X-ray scattering and vibrational spectroscopy

Nucleation and crystallization arising from liquid to solid phase are involved in a multitude of processes in fields ranging from materials science to biology. Controlling the […]
August 17, 2022

Probing hydrogen-bond networks in plastic crystals with terahertz and infrared spectroscopy

A molecular-level understanding of phase changes in hydrogen-bonded solid-state systems is of great importance in fields spanning thermal science to medical therapeutics. Polyols have recently emerged […]
August 14, 2022

Surface Analysis of the Ferri-Ferrocyanide Reaction on Platinum Electrodes With FTIR Using a Spectroelectrochemical Cell

Attenuated total reflection, surface enhanced infrared absorption spectroscopy (ATR-SEIRAS) is a spectrochemical method used to study heterogeneous redox reaction mechanisms. ATR-SEIRAS can detect changes in the […]
June 27, 2022

Role of Mass Transport in the Deposition, Growth, and Transformation of Calcium Carbonate on Surfaces at High Supersaturation

We demonstrate how combined in-situ measurements and finite element method modeling can provide new insight into the relative contribution of mass transport to the growth of […]
June 1, 2022

pH-induced insertion of pHLIP into a lipid bilayer: In-situ SEIRAS characterization of a folding intermediate at neutral pH

The pH low insertion peptide (pHLIP) is a pH-sensitive cell penetrating peptide that transforms from an unstructured coil on the membrane surface at pH > 7, to a transmembrane (TM) […]
April 14, 2022

Effective Medium Approximation for Infrared Surface-Enhancing Substrates

Surface-enhanced infrared absorption spectroscopy (SEIRAS) is an increasingly popular analytical technique for studying molecular adsorption, finding applications in catalysis, biosensing and battery research. Crucial to its […]
April 13, 2022

ATR-SEIRAS Investigation of the Electro-oxidation Mechanism of Biomass-Derived C5 Furanics on Platinum Electrodes

The electrochemical oxidation of furfural and down-pathway intermediate and product species (furoic acid, 2(5H)-furanone, 5-hydroxy-2(5H)-furanone, and maleic acid) is investigated on platinum electrodes via attenuated total […]
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